140165-83-9

Basic information

• Product Name: 2-Pyrrolidinone,1-(1E)-1-propenyl-(9CI)
• Synonyms: 2-Pyrrolidinone,1-(1E)-1-propenyl-(9CI)
• CAS NO: 140165-83-9
• Molecular Formula: C₇H₁₁NO
• Molecular Weight: 125.16834
• Product Categories: PYRROLIDINE
• Mol File: 140165-83-9.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Pyrrolidinone,1-(1E)-1-propenyl-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pyrrolidinone,1-(1E)-1-propenyl-(9CI)(140165-83-9)
• EPA Substance Registry System: 2-Pyrrolidinone,1-(1E)-1-propenyl-(9CI)(140165-83-9)

Safety Data

• Hazardous Substances Data: 140165-83-9(Hazardous Substances Data)

Upstream product

• 2687-97-0 1-allyl-2-pyrrolidinone 
• 4204-66-4 1-(2-hydroxy-propyl)-pyrrolidin-2-one 
• 42366-62-1 1-(2-chloro-propyl)-pyrrolidin-2-one 
• 616-45-5 2-pyrrolidinon 
• 123-38-6 propionaldehyde 

Downstream Products

• 616-45-5 2-pyrrolidinon 

Relevant articles and documents

XtalFluor-E mediated proto-functionalization of: N -vinyl amides: Access to N -acetyl N, O -acetals

XtalFluor-E has been extensively used in a broad range of reactions in the past few years. Here we report its use with protic nucleophiles in a catalytic manner for the in situ generation of protons that lead to the proto-functionalization of activated ol

Nickel-Catalyzed Synthesis of Enamides and Enecarbamates via Isomerization of Allylamides and Allylcarbamates

A single-component, air-stable nickel precatalyst can catalyze the isomerization of allylamides for the synthesis of enamides. The scope of the reaction encompasses various substituted allylamides and allylcarbamates as well as homoallylamides. The reaction can be performed on a multigram-scale without specialized glove-box equipment or Schlenk techniques.

[Pd(μ-Br)(PtBu3)]2 as a highly active isomerization catalyst: Synthesis of enol esters from allylic esters

The dimeric Pd(I)-complex [Pd(μ-Br)(PtBu3)] 2 was found to be highly active for catalyzing double-bond migration in various substrates such as unsaturated ethers, alcohols, amides, and arenes, under mild conditions. It efficiently mediates the conversion of allylic esters into enol esters, rather than inserting into the allylic C-O bond. The broad applicability of this reaction was demonstrated with the synthesis of 22 functionalized enol esters.