140170-13-4

Basic information

• Product Name: (Z)-(2S,3R,8R)-3-(tert-Butyl-diphenyl-silanyloxy)-8-diisopropylsilanyloxy-2-ethyl-9-methylene-2,3,4,7,8,9-hexahydro-oxonine
• Synonyms: (Z)-(2S,3R,8R)-3-(tert-Butyl-diphenyl-silanyloxy)-8-diisopropylsilanyloxy-2-ethyl-9-methylene-2,3,4,7,8,9-hexahydro-oxonine
• CAS NO: 140170-13-4
• Molecular Weight: 550.929
• Mol File: 140170-13-4.mol

Chemical Properties

• CAS DataBase Reference: (Z)-(2S,3R,8R)-3-(tert-Butyl-diphenyl-silanyloxy)-8-diisopropylsilanyloxy-2-ethyl-9-methylene-2,3,4,7,8,9-hexahydro-oxonine(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-(2S,3R,8R)-3-(tert-Butyl-diphenyl-silanyloxy)-8-diisopropylsilanyloxy-2-ethyl-9-methylene-2,3,4,7,8,9-hexahydro-oxonine(140170-13-4)
• EPA Substance Registry System: (Z)-(2S,3R,8R)-3-(tert-Butyl-diphenyl-silanyloxy)-8-diisopropylsilanyloxy-2-ethyl-9-methylene-2,3,4,7,8,9-hexahydro-oxonine(140170-13-4)

Safety Data

• Hazardous Substances Data: 140170-13-4(Hazardous Substances Data)

Upstream product

• 2227-29-4 chlorodiisopropylsilane 
• 140170-12-3 (Z,3R,8R,9S)-8-tert-butyldiphenylsilanyloxy-9-ethyl-3-hydroxy-2-methylene-2,3,4,7,8,9-hexahydrooxonine 

Downstream Products

• 140170-15-6 (+/-)-(Z,2R,3R,8R,9S)-8-tert-butyldiphenylsilanyloxy-9-ethyl-3-hydroxy-2-hydroxymethyl-2,3,4,7,8,9-hexahydrooxonine 
• 140170-15-6 (Z)-(2S,3R,8R,9S)-8-(tert-Butyl-diphenyl-silanyloxy)-9-ethyl-2-hydroxymethyl-2,3,4,7,8,9-hexahydro-oxonin-3-ol 

Relevant articles and documents

An intramolecular hydrosilation approach to hexahydrooxonins related to obtusenyne. Effect of catalyst and conditions on stereoselectivity

The intramolecular hydrosilation of the α-dialkylsilyloxy enol ethers 3 and 5 followed by oxidative workup resulted in the diastereoselective synthesis of either the hexahydrooxonin diol 7 or 8 according to the catalyst and conditions employed.