An intramolecular hydrosilation approach to hexahydrooxonins related to obtusenyne. Effect of catalyst and conditions on stereoselectivity

DOI: 10.1016/S0040-4039(00)92340-2

Source and publish data:

Tetrahedron Letters p. 675 - 678 (1992)

Update date:2022-08-16

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Authors:

Curtis Curtis

Holmes Holmes

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Article abstract of DOI:10.1016/S0040-4039(00)92340-2

The intramolecular hydrosilation of the α-dialkylsilyloxy enol ethers 3 and 5 followed by oxidative workup resulted in the diastereoselective synthesis of either the hexahydrooxonin diol 7 or 8 according to the catalyst and conditions employed.

Full text of DOI:10.1016/S0040-4039(00)92340-2

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