1401735-39-4

Basic information

• Product Name: C₁₆H₂₄O₄
• Synonyms: C₁₆H₂₄O₄
• CAS NO: 1401735-39-4
• Molecular Weight: 280.364
• Mol File: 1401735-39-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₂₄O₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₂₄O₄(1401735-39-4)
• EPA Substance Registry System: C₁₆H₂₄O₄(1401735-39-4)

Safety Data

• Hazardous Substances Data: 1401735-39-4(Hazardous Substances Data)

Upstream product

• 1521-51-3 rac-3-bromocyclohexene 
• 20599-27-3 1-bromopent-2-ene 
• 108-59-8 malonic acid dimethyl ester 

Relevant articles and documents

Chain-walking strategy for organic synthesis: Catalytic cycloisomerization of 1,n-dienes

The catalytic construction of carbon-carbon bonds in small organic molecules via chain walking is described. Catalytic cycloisomerization of 1,n-dienes via chain walking was achieved using a palladium-1,10-phenanthroline catalyst to form five-membered-ring products. By means of a cycloisomerization/ hydrogenation protocol, 1,7- to 1,14-dienes were selectively converted to bicyclo[4.3.0]nonane derivatives. The use of chain walking provides a new method in organic synthesis to functionalize unreactive carbon-hydrogen bonds by letting the catalyst look for preferable bond-forming sites by moving around on the substrate.