140200-31-3Relevant articles and documents
Perfluoro- and Polyfluoro-sulphonic Acids. Part 22. Polyfluorophenyl Pentafluorobenzenesulphonates and their Electron Transfer Reaction with Sodium Iodide
Chen, Qing-Yun,Chen, Ming-Fang
, p. 1071 - 1075 (2007/10/02)
Polyfluorophenyl pentafluorobenzenesulphonates (1) have been synthesized in excellent yields by the reaction of pentafluorobenzenesulphonyl chloride with polyfluorophenoxides.Nucleophilic attack on 1 resulted in the breakage of the S-O bond accompanied by displacement of o- and /or p-fluorine.Reaction of 1 with sodium iodide (8) in a mole ratio of 1:3 (1:8) yielded polyfluorodiphenyl ethers 9 and 10 as the main products.However, p-C6F5OC6F4SO3C6F5 (12) was isolated as the major product in addition to 9 and 10 when the reactant ratio was 1:1 or 1:0.25.Reaction of 12 with sodium iodide also gave 9 and 10 when the reactant ratio was 1:3 (12:8).The reaction of 1 (or 12) with NaI is supposed to be an electron-transfer process.