879-06-1

Upstream product

• 344-07-0 1-chloro-2,3,4,5,6-pentafluorobenzene 
• 925-90-6 ethylmagnesium bromide 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 7719-12-2 phosphorus trichloride 
• 13888-78-3 di-(pentafluoro phenyl) methylsilane 
• 676-58-4 methylmagnesium chloride 
• 1068-55-9 isopropylmagnesium chloride 
• 13888-77-2 (pentafluorophenyl)dimethylsilane 

Downstream Products

• 25202-37-3 pentafluorophenylvinyldiethoxysilane 
• 79505-98-9 5-Oxo-5-pentafluorophenyl-pentanoic acid ethyl ester 
• 79505-99-0 1,5-Bis-pentafluorophenyl-pentane-1,5-dione 
• 19349-34-9 1,6-Bis-(pentafluorphenyl)-hexandion-(1,6) 
• 79506-00-6 6-Oxo-6-pentafluorophenyl-hexanoic acid ethyl ester 
• 79506-01-7 6-Hydroxy-6,6-bis-pentafluorophenyl-hexanoic acid ethyl ester 
• 116547-16-1 ethyl ester of 1-pentafluorophenylhydroxymethylcyclopropane-1-carboxylic acid 
• 89386-82-3 5-endo-Hydroxy-5-pentafluorophenyl-2,3-tetrafluorobenzobicyclo<2.2.2>octa-2,7-diene 
• 89386-82-3 5-exo-Hydroxy-5-pentafluorophenyl-2,3-tetrafluorobenzobicyclo<2.2.2>octa-2,7-diene 
• 89386-83-4 5-exo-Hydroxy-5-pentafluorophenyl-2,3-tetrafluorobenzobicyclo<2.2.2>oct-2-ene 
• 89386-85-6 2-Hydroxy-2-pentafluorophenyl-6,7-tetrafluorobenzobicyclo<3.2.1>octa-3,6-diene 
• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 
• 832-53-1 pentafluorobenzenesulonyl chloride 
• 79505-93-4 ethyl α-pentafluorobenzoylisobutyrate 

Relevant academic research and scientific papers

Method of making chlorofluoroethers

A method is provided for preparation of chlorofluoroethers ClCF2CFClOR8f and Cl2CFCFClOR8f by direct fluorination of Cl2CHCH2OR8 and Cl3CCH2OR8, respectively, wherein R8 is a C1-C20 alkyl-or acyl-containing group optionally up to 5 ether oxygen atoms and optionally substituted by functional groups and R81, is the corresponding perfluoroalkyl or perfluoracyl-containing group.

Halogenated acrylates and polymers derived therefrom

Acrylates having a high degree of halogenation, as well as polymers that include one or more mer units derived from such acrylates provide materials having tailorable optical and physical properties. The polymers find utility particularly in optical devic

Perfluoro- and Polyfluoro-sulphonic Acids. Part 22. Polyfluorophenyl Pentafluorobenzenesulphonates and their Electron Transfer Reaction with Sodium Iodide

Polyfluorophenyl pentafluorobenzenesulphonates (1) have been synthesized in excellent yields by the reaction of pentafluorobenzenesulphonyl chloride with polyfluorophenoxides.Nucleophilic attack on 1 resulted in the breakage of the S-O bond accompanied by displacement of o- and /or p-fluorine.Reaction of 1 with sodium iodide (8) in a mole ratio of 1:3 (1:8) yielded polyfluorodiphenyl ethers 9 and 10 as the main products.However, p-C6F5OC6F4SO3C6F5 (12) was isolated as the major product in addition to 9 and 10 when the reactant ratio was 1:1 or 1:0.25.Reaction of 12 with sodium iodide also gave 9 and 10 when the reactant ratio was 1:3 (12:8).The reaction of 1 (or 12) with NaI is supposed to be an electron-transfer process.