1402012-56-9

Basic information

• Product Name: 4-chlorophenyl 3,4-dihydronaphthalene-2-carboxylate
• Synonyms: 4-chlorophenyl 3,4-dihydronaphthalene-2-carboxylate
• CAS NO: 1402012-56-9
• Molecular Weight: 284.742
• Mol File: 1402012-56-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-chlorophenyl 3,4-dihydronaphthalene-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-chlorophenyl 3,4-dihydronaphthalene-2-carboxylate(1402012-56-9)
• EPA Substance Registry System: 4-chlorophenyl 3,4-dihydronaphthalene-2-carboxylate(1402012-56-9)

Safety Data

• Hazardous Substances Data: 1402012-56-9(Hazardous Substances Data)

Upstream product

• 1988-22-3 4-chlorophenyl formate 
• 143139-14-4 trifluoromethanesulfonic acid 3,4-dihydronaphthalen-2-yl ester 
• 530-93-8 1,2,3,4-tetrahydronaphthalen-2-one 
• 106-48-9 4-chloro-phenol 

Relevant articles and documents

Trichlorophenyl formate: Highly reactive and easily accessible crystalline CO surrogate for palladium-catalyzed carbonylation of aryl/alkenyl halides and triflates

The high utility of 2,4,6-trichlorophenyl formate, a highly reactive and easily accessible crystalline CO surrogate, is demonstrated. The decarbonylation with NEt3 to generate CO proceeded rapidly at rt, thereby allowing external-CO-free Pd-catalyzed carbonylation of aryl/alkenyl halides and triflates. The high reactivity of the CO surrogate enabled carbonylation at rt and significantly reduced the quantities of formate to near-stoichiometric levels. The obtained trichlorophenyl esters can be readily converted to a variety of carboxylic acid derivatives in high yields.