1402147-70-9Relevant academic research and scientific papers
A synthesis of echinopine B
Michels, Theo D.,Dowling, Matthew S.,Vanderwal, Christopher D.
, p. 7572 - 7576 (2012)
In a short synthesis of echinopine B, a guaiane-like intermediate was generated through a methylenecyclopentane annulation onto a substituted cycloheptenone. The resulting bicyclic compound was converted into the natural product by a PtCl2-catalyzed enyne cycloisomerization (see scheme). Several late-stage polycyclic rearrangement products were isolated and characterized. Copyright
