14090-60-9

Basic information

• Product Name: Cyclopentanone dimethyl hydrazone
• Synonyms: Cyclopentanone dimethyl hydrazone
• CAS NO: 14090-60-9
• Molecular Formula: C₇H₁₄N₂
• Molecular Weight: 126.2
• Mol File: 14090-60-9.mol
• Article Data: 19

Chemical Properties

• Boiling Point: 180.1°C at 760 mmHg
• Flash Point: 62.7°C
• Appearance: /
• Density: 0.96g/cm³
• Vapor Pressure: 0.909mmHg at 25°C
• Refractive Index: 1.509
• CAS DataBase Reference: Cyclopentanone dimethyl hydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopentanone dimethyl hydrazone(14090-60-9)
• EPA Substance Registry System: Cyclopentanone dimethyl hydrazone(14090-60-9)

Safety Data

• Hazardous Substances Data: 14090-60-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H14N2/c1-9(2)8-7-5-3-4-6-7/h3-6H2,1-2H3

Upstream product

• 120-92-3 cyclopentanone 
• 593-82-8 N,N-dimethylhydrazine hydrochloride 
• 35758-82-8 1,1-dimethyldiazenium bromide 
• 1741-01-1 Trimethylhydrazin 
• 57-14-7 N,N-Dimethylhydrazine 

Downstream Products

• 30079-93-7 2-allylcyclopentanone 
• 120-92-3 cyclopentanone 
• 13074-65-2 2-hexylcyclopentanone 
• 328534-03-8 2-(4'-phenylbutyl)cyclopentanone 
• 162369-31-5 2-(3-phenylpropyl)cyclopentanone 
• 328534-04-9 2-(5'-phenylpentyl)cyclopentanone 
• 412034-81-2 2-pent-3-yn-1-ylcyclopentanone 
• 88726-43-6 (3α,3aβ,6aβ)-3-ethenylhexahydro-3a(1H)-pentalenol 
• 211234-53-6 [2-(3-Benzyloxy-propyl)-cyclopent-1-enyloxy]-trimethyl-silane 
• 211234-54-7 [2-(4-Benzyloxy-butyl)-cyclopent-1-enyloxy]-trimethyl-silane 
• 211234-55-8 [2-(5-Benzyloxy-pentyl)-cyclopent-1-enyloxy]-trimethyl-silane 
• 211234-64-9 [5-(3-Benzyloxy-propyl)-bicyclo[3.1.0]hex-1-yloxy]-trimethyl-silane 
• 211234-65-0 [5-(4-Benzyloxy-butyl)-bicyclo[3.1.0]hex-1-yloxy]-trimethyl-silane 
• 211234-66-1 [5-(5-Benzyloxy-pentyl)-bicyclo[3.1.0]hex-1-yloxy]-trimethyl-silane 

Relevant articles and documents

α-carbonyl radical cyclization approach toward spiro[4.4]nonene: Total synthesis of dimethyl gloiosiphone A

The total synthesis of dimethyl gloiosiphone A 2 was achieved via an α-carbonyl radical spirocyclization.

Intramolecular cycloadditions of vinylketenes to olefins. Part II. The synthesis of a linear annelated triquinane derivative.

Regioselective formation of vinylketene 3, followed by its stereoselective intramolecular cycloaddition with an olefin, yielded the linear annelated cis-anti-cis triquinane precursor 1.

Tertiary Enamide-Triggered SEAr: Domino Allylation and Enamine-Type Addition

Two unprecedented domino reactions are described, starting from ketospiro-enesulfonamides. By treatment with ZrCl4 and allylsilane, an intramolecular electrophilic aromatic substitution and subsequent allylation is observed. By treatment with TiCl4 and allylsilane, a double enamine-type reaction takes place, thus creating simultaneously four contiguous stereogenic centers diastereoselectively.

Enantioselective Conia-Ene-Type Cyclizations of Alkynyl Ketones through Cooperative Action of B(C6F5)3, N-Alkylamine and a Zn-Based Catalyst

An efficient and highly enantioselective Conia-ene-type process has been developed. Reactions are catalyzed by a combination of B(C6F5)3, an N-alkylamine and a BOX-ZnI2 complex. Specifically, through cooperative

One-pot sequential 1,4- and 1,2-reductions of α,β-unsaturated δ-lactones to the corresponding δ-lactols with CuCl and NaBH 4 in methanol

An efficient, one-pot method for the highly chemoselective synthesis of δ-lactols from α,β-unsaturated δ-lactones using CuCl and NaBH4 in methanol was developed. Georg Thieme Verlag Stuttgart. New York.