1402235-26-0

Basic information

• Product Name: (Z)-2-(1-(3-methylphenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: (Z)-2-(1-(3-methylphenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1402235-26-0
• Molecular Weight: 258.168
• Mol File: 1402235-26-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (Z)-2-(1-(3-methylphenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-(1-(3-methylphenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1402235-26-0)
• EPA Substance Registry System: (Z)-2-(1-(3-methylphenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1402235-26-0)

Safety Data

• Hazardous Substances Data: 1402235-26-0(Hazardous Substances Data)

Upstream product

• 29816-85-1 1-methyl-3-(propa-1,2-dien-1-yl)benzene 
• 73183-34-3 bis(pinacol)diborane 
• 1402235-30-6 2-(3-(3-methylphenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 18826-62-5 1-methyl-3-(prop-1-yn-1-yl)benzene 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Relevant articles and documents

Pincer Iron Hydride Complexes for Alkene Isomerization: Catalytic Approach to Trisubstituted (Z)-Alkenyl Boronates

An iron dichloride complex [Fe]Cl2 supported by a pincer phosphine-pyridine-imidazoline (PNNimid) ligand {[Fe]Cl2 = (PNNimid)FeCl2}, upon activation with NaHBEt3, catalyzes the isomerization of 1,1-disubstituted alkenyl boronates to synthetically valuable

Ligand controlled highly selective copper-catalyzed borylcuprations of allenes with bis(pinacolato)diboron

Copper-catalyzed highly selective borylcuprations of allenes with bis(pinacolato)diboron produce two different types of alkenylboranes by applying a ligand effect. In the presence of tris(para-methoxyphenyl)phosphine [P(C 6H4OMe-p)3], the reaction of aryl-1,2-dienes affords 2-alken-2-yl boronates as the only product with exclusive Z-geometry; the regioselectivity is switched to afford the 1-alken-2-yl boronates as the major products when the bidentate phosphine 2,2'-bis(diphenylphosphino)biphenyl is used as the ligand. Copyright