140231-68-1Relevant academic research and scientific papers
Mechanochemical arylation and alkylation of fullerene C60 under the solvent-free conditions
Tanaka, Toru,Komatsu, Koichi
, p. 4397 - 4402 (1999)
The mechanochemical reaction of fullerene C60 with organic bromides and alkali metals was found to give the corresponding aryl or alkyl C60 derivatives under the solvent-free conditions.
Design of fullerene derivatives for stabilizing LUMO energy using donor groups placed in spatial proximity to the C60 cage
Matsumoto, Fukashi,Iwai, Toshiyuki,Moriwaki, Kazuyuki,Takao, Yuko,Ito, Takatoshi,Mizuno, Takumi,Ohno, Toshinobu
, p. 9038 - 9043,6 (2012/12/12)
A series of arylated dihydrofullerene derivatives were synthesized to elucidate the effective design of fullerene derivatives for enhancing the performance of organic photovoltaics. The LUMO energy of the fullerenes was estimated by the first reduction po
Selective introduction of organic groups to C60 and C 70 using organoboron compounds and rhodium catalyst: A new synthetic approach to organo(hydro)fullerenes
Nambo, Masakazu,Segawa, Yasutomo,Wakamiya, Atsushi,Itami, Kenichiro
supporting information; scheme or table, p. 590 - 598 (2011/10/12)
A Rh-catalyzed reaction of C60 and C70 with organoboron compounds is described. This new catalytic method enables introduction of various organic groups onto C60 and C70. [Rh(cod)(MeCN)2]BF4/sub
AlCl3-catalyzed tandem acetylation of hydroarylated [60]fullerenes
Kokubo, Ken,Tochika, Shinya,Kato, Mai,Sol, Yui,Oshima, Takumi
supporting information; experimental part, p. 3335 - 3338 (2009/05/11)
(Chemical Equation Presented) The AlCl3-catalyzed acetylation of 1,2-hydrophenylated [60]fullerenes, HC60-Ar, proceeded via a sequential manner involving the acetylation at the hydrogenated fullerene carbon, the following intramolecu
A bench-stable Pd catalyst for the hydroarylation of fullerene with boronic acids
Mori, Susumu,Nambo, Masakazu,Chi, Liang-Chen,Bouffard, Jean,Itami, Kenichiro
scheme or table, p. 4609 - 4612 (2009/05/26)
(Chemical Equation Presented) A Pd(II) catalyst for the hydroarylation of fullerene with boronic acids is presented. Treatment of C60 with an arylboronic acid in the presence of a catalytic amount of Pd(2-PyCH=NPh) (OCOC6F5/sub
Rh-catalyzed arylation and alkenylation of C60 using organoboron compounds
Nambo, Masakazu,Noyori, Ryoji,Itami, Kenichiro
, p. 8080 - 8081 (2008/02/09)
A new organoboron-based arylation and alkenylation of C60 catalyzed by a rhodium complex was developed. A treatment of C60 with an organoboron compound in the presence of a catalytic amount of [Rh(cod)(CH3CN)2]B
