14024-61-4 Usage
Uses
1. Used in Anticancer Applications:
Bis(2,4-pentanedionato-O,O')palladium(II) is used as an active anticancer agent for its growth inhibitory effects, which are more potent than those of cisplatin in several cancer cells. Treatment with Bis(2,4-pentanedionato-O,O')palladium(II) inhibits H460 cells, making it a promising candidate for cancer treatment.
2. Used in Catalyst Applications:
Bis(2,4-pentanedionato-O,O')palladium(II) is used as a catalyst for various organic transformations. It has been employed in the following studies:
a. In the preparation of monodisperse CuPd alloy nanoparticles (NPs) using a typical high-temperature organic solution phase protocol.
b. In the preparation of [(NHC)Pd(acac)L] complexes (where L=Me, NHC = N-heterocyclic carbene), which efficiently catalyze the Heck reaction of activated aryl bromides.
c. As a catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides, facilitating important chemical reactions in the synthesis of various compounds.
Flammability and Explosibility
Highlyflammable
Purification Methods
It can be recrystallised from *C6H6/pet ether and sublimes in vacuo. It is soluble in heptane, *C6H6 (1.2% at 20o, 2.2 at 40o), toluene (0.56% at 20o, 1.4% at 40o) and acetylacetone (1.2% at 20o, 0.05% at 40o). [West & Riley J Inorg Nucl Chem 5 295 1957/8, Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3676.]
Check Digit Verification of cas no
The CAS Registry Mumber 14024-61-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,0,2 and 4 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 14024-61:
(7*1)+(6*4)+(5*0)+(4*2)+(3*4)+(2*6)+(1*1)=64
64 % 10 = 4
So 14024-61-4 is a valid CAS Registry Number.
InChI:InChI=1/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
