1402732-48-2Relevant academic research and scientific papers
Carbon nitride-catalyzed photoredox C-C bond formation with N-aryltetrahydroisoquinolines
Moehlmann, Lennart,Baar, Moritz,Riess, Julian,Antonietti, Markus,Wang, Xinchen,Blechert, Siegfried
, p. 1909 - 1913 (2012)
In this communication we describe the oxidative C-C bond formation of tertiary amines with various nucleophiles under very mild and environmental friendly conditions by using mesoporous graphitic carbon nitride (mpg-C 3N4) semiconduc
The Photocatalyst-Free Cross-Dehydrogenative Coupling Reaction Enabled by Visible-Light Direct Excitation of Substrate
Guo, Xuan,Shao, Bing-Ru,Jiang, Wen-Feng,Shi, Lei
, p. 15743 - 15752 (2021/11/16)
A new photocatalyst-free strategy for the cross-dehydrogenative C-C and C-P coupling reaction has been described. This protocol provides a concise method to synthesize various 1-substituted tetrahydroisoquinoline (THIQ) derivatives enabled by visible-ligh
Carbazole-triazine based donor-acceptor porous organic frameworks for efficient visible-light photocatalytic aerobic oxidation reactions
Luo, Jian,Lu, Jingzhi,Zhang, Jian
supporting information, p. 15154 - 15161 (2018/08/17)
We report the synthesis of a series of carbazole-triazine based donor-acceptor (D-A) POFs and their photocatalytic activities for aerobic oxidation reactions. The simultaneous introduction of a carbazole-based electron donor and a triazine-based electron acceptor in D-A POFs stabilizes the charge transfer state and enables an efficient triplet-triplet energy transfer to generate 1O2. Meanwhile, systematic variation of the D-A distance results in the tunable photoredox properties and consequently the efficiency for generation of reactive oxygen species (ROSs). Upon visible light excitation, all three D-A POFs exhibit excellent capability to promote three aerobic oxidations: sulfide oxidation, oxidative amine coupling, and Mannich reactions. This systematic study validates the design principle of D-A POFs as high-performance photo-oxidation catalysts with wide substrate scope and excellent stability and recyclability.
