1402909-83-4

Basic information

• Product Name: (4S,5R)-isopropyl 5-acetyl-1-(4-methoxyphenylsulfonyl)-4-phenyl-1,4,5,6-tetrahydropyridine-2-carboxylate
• Synonyms: (4S,5R)-isopropyl 5-acetyl-1-(4-methoxyphenylsulfonyl)-4-phenyl-1,4,5,6-tetrahydropyridine-2-carboxylate
• CAS NO: 1402909-83-4
• Molecular Weight: 457.547
• Mol File: 1402909-83-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4S,5R)-isopropyl 5-acetyl-1-(4-methoxyphenylsulfonyl)-4-phenyl-1,4,5,6-tetrahydropyridine-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,5R)-isopropyl 5-acetyl-1-(4-methoxyphenylsulfonyl)-4-phenyl-1,4,5,6-tetrahydropyridine-2-carboxylate(1402909-83-4)
• EPA Substance Registry System: (4S,5R)-isopropyl 5-acetyl-1-(4-methoxyphenylsulfonyl)-4-phenyl-1,4,5,6-tetrahydropyridine-2-carboxylate(1402909-83-4)

Safety Data

• Hazardous Substances Data: 1402909-83-4(Hazardous Substances Data)

Upstream product

• 78-94-4 methyl vinyl ketone 
• 1129-26-6 4-methoxybenzene sulfonamide 
• 111160-44-2 i-propyl 2-oxo-4-phenylbut-3-enoate 

Downstream Products

• 1402910-11-5 (2R,3S,4S,5R)-isopropyl 5-acetyl-2,3-dihydroxy-1-(4-methoxyphenylsulfonyl)-4-phenylpiperidine-2-carboxylate 

Relevant articles and documents

Catalytic asymmetric [4+2] annulation initiated by an aza-rauhut-currier reaction: Facile entry to highly functionalized tetrahydropyridines

Under control: The first example of chiral amino phosphine catalysts for the title reaction between vinyl ketones and N-sulfonyl-1-aza-1,3-dienes has been developed. Under ambient conditions, this protocol provides straightforward access to densely functionalized, enantioenriched tetrahydropyridines with high levels of sterecontrol in good to excellent yields. Copyright