1402934-26-2Relevant academic research and scientific papers
Dual Cobalt and Photoredox Catalysis Enabled Intermolecular Oxidative Hydrofunctionalization
Sun, Han-Li,Wang, Jun-Jie,Yang, Fan,Ye, Wei-Ting,Zhu, Rong
, p. 4983 - 4989 (2020)
A general protocol has been developed for the Markovnikov-selective intermolecular hydrofunctionalization based on visible-light-mediated Co/Ru dual catalysis. The key feature involves the photochemical oxidation of an organocobalt(III) intermediate deriv
Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway
Zhou, Xiao-Le,Yang, Fan,Sun, Han-Li,Yin, Yun-Nian,Ye, Wei-Ting,Zhu, Rong
supporting information, p. 7250 - 7255 (2019/05/16)
A functional group tolerant cobalt-catalyzed method for the intermolecular hydrofunctionalization of alkenes with oxygen- and nitrogen-based nucleophiles is reported. This protocol features a strategic use of hypervalent iodine(III) reagents that enables a mechanistic shift from conventional cobalt-hydride catalysis. Key evidence was found supporting a unique bimetallic-mediated rate-limiting step involving two distinct cobalt(III) species, from which a new carbon-heteroatom bond is formed.
A novel metal-free reductive esterification of N-tosylhydrazones with carboxylic acids
Zhou, Ankun,Wu, Lei,Li, Dazhi,Chen, Qingqing,Zhang, Xiao,Xia, Wujiong
, p. 1862 - 1866 (2012/10/29)
A novel method for the synthesis of esters via reductive coupling of N-tosylhydrazones with carboxylic acids under metal-free conditions has been developed. Various functional groups were found to be tolerable under the reaction conditions to afford low to good yields.
