1403471-04-4Relevant articles and documents
Functionalization of tetraorganosilanes and permethyloligosilanes at a methyl group on silicon via iridium-catalyzed C(sp3)-H borylation
Ohmura, Toshimichi,Torigoe, Takeru,Suginome, Michinori
, p. 6170 - 6173 (2013)
In the presence of an iridium 3,4,7,8-tetramethyl-1,10-phenanthroline catalyst, a methyl group on the silicon atom of alkyltrimethylsilanes undergoes selective C-H borylation with bis(pinacolato)diboron in cyclooctane at 135 C to give alkyl(borylmethyl)dimethylsilanes. The C-H borylation of tetramethylsilane takes place efficiently at 100 C. Permethyloligosilanes can also undergo C-H borylation without cleavage of the Si-Si bonds.
Catalytic functionalization of methyl group on silicon: Iridium-catalyzed C(sp3)-H borylation of methylchlorosilanes
Ohmura, Toshimichi,Torigoe, Takeru,Suginome, Michinori
supporting information, p. 17416 - 17419,4 (2012/12/12)
A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 °C, giving (borylmethyl)chlorosilanes selectively.