1403475-03-5Relevant academic research and scientific papers
Copper-catalyzed three-component reactions of phenols, acyl chlorides and Wittig reagents for the synthesis of β-aryloxyl acrylates
Zhang, Yi,Liu, Yunyun,Wan, Jie-Ping
, p. 1567 - 1569 (2015)
The synthesis of aryloxyl acrylates has been achieved through a new three-component synthetic method involving the assembly of phenols, acyl chlorides and Wittig reagents in the presence of a copper catalyst using glucose as a green ligand. β-Aryloxyl acrylates have been prepared with high diversity and in good to excellent yields involving the cascade formation of a new CC bond and a C(sp2)-O bond.
Stereoselective synthesis of (E)-?-aryloxyl and alkyloxyl acrylates through DABCO-catalysed Michael additions of phenols and alcohols to ethyl 2,3-butadienoate
Wei, Feng,Haibo, Wu,Houjun, Qian,Zhengyi, Li,Xiaoqiang, Sun,Zhiming, Wang
, p. 364 - 367 (2016/07/06)
The development of DABCO-catalysed Michael addition of phenols and alcohols to ethyl 2,3-butadienoate provides an efficient synthetic pathway to (E)-?-aryloxyl and alkyloxyl acrylates in i-PrOH or under solvent-free conditions. The major advantages of the present method are wide substrate scope, mild reaction conditions, high stereoselectivity, and good reaction yields.
