1403588-86-2Relevant academic research and scientific papers
Synthesis of β-C-galactosyl d- and l-alanines
Thota, V. Narasimharao,Kulkarni, Suvarn S.,Gervay-Hague, Jacquelyn
, p. 8132 - 8139,8 (2012/12/11)
Synthesis of β-C-d-galactosyl d- and l-alanines is carried out via a highly stereoselective Grignard reaction of glycosyl iodides, Sharpless dihydroxylation and SN2 displacement of the corresponding mesylate or tosylate. Alternatively, attempted triflation of the intermediate alcohols triggers a stereoselective debenzylative cyclization leading to interesting bicyclic trans-fused compounds.
