1403588-87-3

Basic information

• Product Name: (S)-methyl 2-azido-3-((2S,3S,4R,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl) tetrahydro-2H-pyran-2-yl)-propanoate
• Synonyms: (S)-methyl 2-azido-3-((2S,3S,4R,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl) tetrahydro-2H-pyran-2-yl)-propanoate
• CAS NO: 1403588-87-3
• Molecular Weight: 651.759
• Mol File: 1403588-87-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-methyl 2-azido-3-((2S,3S,4R,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl) tetrahydro-2H-pyran-2-yl)-propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-methyl 2-azido-3-((2S,3S,4R,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl) tetrahydro-2H-pyran-2-yl)-propanoate(1403588-87-3)
• EPA Substance Registry System: (S)-methyl 2-azido-3-((2S,3S,4R,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl) tetrahydro-2H-pyran-2-yl)-propanoate(1403588-87-3)

Safety Data

• Hazardous Substances Data: 1403588-87-3(Hazardous Substances Data)

Upstream product

• 179090-11-0 (3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]tetrahydro-2H-pyran-2-one 
• 1403588-86-2 1-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)-(2S)-azido-3-tert-butyldiphenylsilyloxypropane 
• 1403588-82-8 1-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)-(2R)-ol-3-tert-butyldiphenylsilyloxypropane 
• 67-56-1 methanol 
• 1403614-60-7 1-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)-(2S)-azido-3-propanol 

Downstream Products

• 1403588-88-4 methyl 3C-β-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)-N-tert-butoxycarbonyl-L-alanine 

Relevant articles and documents

Synthesis of β-C-Glycosyl Amino Acids by Ring Opening of Donor-Acceptor Spiro-cyclopropanecarboxylated Sugars

The electrophilic ring opening of donor-acceptor spiro-cyclopropanecarboxylated sugars are shown to provide easy access to the stereoselective synthesis of β-C-glycosyl D- and L-alanine derivatives. A possible mechanism is proposed for the ring-opening reaction based on the obtained crystal structure of one of the spiro-cyclic sugar moieties.