14038-13-2

Basic information

• Product Name: 1-methoxy-2-(pentafluoroethyl)benzene
• Synonyms: 1-methoxy-2-(pentafluoroethyl)benzene
• CAS NO: 14038-13-2
• Molecular Weight: 226.146
• Mol File: 14038-13-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-methoxy-2-(pentafluoroethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-2-(pentafluoroethyl)benzene(14038-13-2)
• EPA Substance Registry System: 1-methoxy-2-(pentafluoroethyl)benzene(14038-13-2)

Safety Data

• Hazardous Substances Data: 14038-13-2(Hazardous Substances Data)

Upstream product

• 2314-97-8 iodotrifluoromethane 
• 578-57-4 2-bromoanisole 
• 60007-39-8 pentafluoroethylcopper(I) 
• 529-28-2 4-iodoanisol 
• 77758-76-0 phenyl(pentafluoroethyl)iodonium triflate 
• 100-66-3 methoxybenzene 

Relevant articles and documents

"ligandless" Pentafluoroethylation of Unactivated (Hetero)aryl and Alkenyl Halides Enabled by the Controlled Self-Condensation of TMSCF3-Derived CuCF3

Pentafluoroethylation of unactivated C(sp2)-X bonds (X = I, Br) using a storable, "ligandless" CuC2F5 reagent prepared by controlled self-condensation of ready available TMSCF3-derived CuCF3 has been

Pentafluoroethylating compositions

The present invention relates to pentafluoroethylating compositions, processes for obtaining them, and their use in pentafluoroethylation reactions.

Cupration of C2F5H: Isolation, structure, and synthetic applications of [K(DMF)2][(t -BuO)Cu(C2F 5)]. Highly efficient pentafluoroethylation of unactivated aryl bromides

Pentafluoroethane, C2F5H (HFC-125), is smoothly cuprated with preisolated or in situ-generated [K(DMF)][(t-BuO)2Cu] to give [K(DMF)2][(t-BuO)Cu(C2F5)] (1) in nearly quantitative yield. Complex 1 has been isolated, structurally characterized, and demonstrated to be an exceedingly versatile pentafluoroethylating reagent for a variety of substrates, including unactivated aryl bromides.