1404226-37-4

Basic information

• Product Name: C₁₈H₂₀O₂S
• Synonyms: C₁₈H₂₀O₂S
• CAS NO: 1404226-37-4
• Molecular Weight: 300.422
• Mol File: 1404226-37-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₈H₂₀O₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₂₀O₂S(1404226-37-4)
• EPA Substance Registry System: C₁₈H₂₀O₂S(1404226-37-4)

Safety Data

• Hazardous Substances Data: 1404226-37-4(Hazardous Substances Data)

Upstream product

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Relevant articles and documents

Cu-doped zeolitic imidazolate framework catalysed highly selective conversion of alkynes to β -keto and vinyl sulfones using sodium sulfinates

Abstract: Cu 2 +-doped zeolitic imidazolate framework-8 (ZIF-8)-catalyzed one-pot procedure to synthesize β -keto and vinyl sulfones by the direct oxysulfonylation and hydrosulfonylation of alkynes via radical reaction under mild conditions has been described. The advantages of this protocol included broad substrate scope and excellent β -keto and E-stereoselectivity. The Cu/ZIF-8 catalyst not only exhibited excellent performance but also had a great stability in the reaction, successfully allowing its reuse up to five cycles. This efficient Cu/ZIF-8 heterogeneous catalyst is explored for the first time to generate β -keto and vinyl sulfones. Graphical Abstract:: Cu 2 +-doped zeolitic imidazolate framework-8 (ZIF-8)-catalyzed one-pot procedure to synthesize β -keto and vinyl sulfones by the direct oxysulfonylation and hydrosulfonylation of alkynes via radical reaction under mild conditions is described. The advantages of this protocol included broad substrate scope and excellent β -keto and E-stereoselectivity. This efficient Cu/ZIF-8 heterogeneous catalyst is explored for the first time for C-S bond formation. [Figure not available: see fulltext.].