1404432-58-1

Basic information

• Product Name: 4-bromo-1-iodo-2-(prop-1-en-2-yl)benzene
• Synonyms: 4-bromo-1-iodo-2-(prop-1-en-2-yl)benzene
• CAS NO: 1404432-58-1
• Molecular Weight: 322.971
• Mol File: 1404432-58-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-bromo-1-iodo-2-(prop-1-en-2-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-bromo-1-iodo-2-(prop-1-en-2-yl)benzene(1404432-58-1)
• EPA Substance Registry System: 4-bromo-1-iodo-2-(prop-1-en-2-yl)benzene(1404432-58-1)

Safety Data

• Hazardous Substances Data: 1404432-58-1(Hazardous Substances Data)

Upstream product

• 1261648-81-0 1-(5-bromo-2-iodophenyl)ethanone 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 181765-86-6 5-bromo-2-iodo-benzoic acid methyl ester 

Downstream Products

• 1404432-69-4 6-bromo-1-(iodomethyl)-1-methyl-2,3-diphenyl-1H-indene 

Relevant articles and documents

Enantioselective Cross-Exchange between C?I and C?C σ Bonds

A palladium-catalyzed enantioselective intramolecular σ-bond cross-exchange between C?I and C?C bonds is realized, providing chiral indanones bearing an alkyl iodide group and an all-carbon quaternary stereocenter. Pd/TADDOL-derived phosphoramidite is found to be an efficient catalytic system for both C?C bond cleavage and alkyl iodide reductive elimination. In addition to aryl iodides, aryl bromides can also be used for this transformation in the presence of KI. Density-functional theory (DFT) calculation studies support the ring-opening of cyclobutanones occuring through an oxidative addition/reductive elimination process involving PdIV species.