14060-53-8

Usage

InChI:InChI=1/C22H24N2/c1-23(2)20-13-9-18(10-14-20)22(17-7-5-6-8-17)19-11-15-21(16-12-19)24(3)4/h5-16H,1-4H3

Upstream product

• 90-94-8 bis(p-dimethylaminophenyl)methanone 
• 4984-82-1 sodium cyclopentadienylide 
• 16733-97-4 cyclopentadienyllithium 
• 542-92-7 cyclopenta-1,3-diene 

Downstream Products

• 82385-02-2 [6,6-Bis[4-(dimethylamino)phenyl]fulven](1,5-cyclooctadien)nickel⁽⁰⁾ 
• 165681-52-7 [(1-3-η):(1-3-η)-4,4'-bis[bis(4-(dimethylamino)phenyl)methylidene]-5,5'-dihydrofulvalene]hexakis(trimethylphosphino)dicobalt(I) 
• 165681-57-2 [(1-4-η)-6,6-bis(4-(dimethylamino)phenyl)fulvene]phenylbis(trimethylphosphine)cobalt(I) 
• 165822-99-1 [(1-4-η)-6,6-bis(4-(dimethylamino)phenyl)fulvene]methylbis(trimethylphosphine)cobalt(I) 

Relevant academic research and scientific papers

Uebergangsmetall-Fulven-Komplexe XXXIII. Synthese und Struktur von Fulven-Komplexen des Cobalts und Rhodiums

Diarylfulvenes react with (C5H5)Co(C2H4)2 to give the η4-coordinated fulvene complexes (C5H5)2Co(fulvene) (3).Reaction of (C5H5)Rh(C2H4)2 or (C9H7)Rh(C2H4)2 (C9H7 = indenyl) with diphenylfulvene yields the compounds (C5H5)Rh(η4-fulve

Process for producing ethylene/α-olefin copolymer

A process capable of producing an ethylene/α-olefin copolymer having a high molecular weight even under the conditions of a high polymerization temperature is provided. The process for producing an ethylene/α-olefin copolymer includes copolymerizing ethyl

Method for producing fulvene

PROBLEM TO BE SOLVED: To provide a method for producing a fulvene in which the reaction efficiently proceeds regardless of the nature of the substituent group which a raw-material ketone, especially a ketone not having an α-proton, possesses. SOLUTION: Provided is a method for producing a fulvene including a step to condense a ketone not possessing an α-proton, and an alkali metal salt of cyclopentadiene in the presence of a Lewis acid. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT

Transition Metal Fulvene Complexes, XVIII. On (Fulvene)nickel(0) Complexes. Structure Comparison of (1,5-Cyclooctadiene)(6,6-diphenylfulvene)nickel and Tricarbonyl(6,6-diphenylfulvene)iron

Bis(1,5-cyclooctadiene)nickel reacts with 6,6-diarylfulvenes to give compounds of the type (1,5-cyclooctadiene)(6,6-diarylfulvene)nickel(0) (2).The complex (1,5-cyclooctadiene)(6,6-diphenylfulvene)nickel(0)*1/2 cyclohexane (2a) has been characterized by an X-ray analysis and is compared with the structure of tricarbonyl(6,6-diphenylfulvene)iron (4).The coordinated cyclooctadiene in 2a is easily exchanged by other ligands such as 2,2'-bipyridine.