82385-02-2Relevant academic research and scientific papers
Transition Metal Fulvene Complexes, XVIII. On (Fulvene)nickel(0) Complexes. Structure Comparison of (1,5-Cyclooctadiene)(6,6-diphenylfulvene)nickel and Tricarbonyl(6,6-diphenylfulvene)iron
Edelmann, Frank,Lubke, Bernhard,Behrens, Ulrich
, p. 1325 - 1331 (2007/10/02)
Bis(1,5-cyclooctadiene)nickel reacts with 6,6-diarylfulvenes to give compounds of the type (1,5-cyclooctadiene)(6,6-diarylfulvene)nickel(0) (2).The complex (1,5-cyclooctadiene)(6,6-diphenylfulvene)nickel(0)*1/2 cyclohexane (2a) has been characterized by an X-ray analysis and is compared with the structure of tricarbonyl(6,6-diphenylfulvene)iron (4).The coordinated cyclooctadiene in 2a is easily exchanged by other ligands such as 2,2'-bipyridine.
