140671-94-9Relevant academic research and scientific papers
Synthesis and X-Ray Crystallographic Characterisation of the Diphosphane bridged Cluster
Nicholls, J. Nicola,Raithby, Paul R.,Vargas, Maria D.
, p. 1617 - 1619 (1986)
Deprotonation of followed by oxidation with Ag in the presence of (+) affords the cluster , which has been shown by X-ray analysis to contain an Ir4 and an Ir4Au2 unit linked by a diphosphane (PhPPPh) ligand.
Synthesis and Mechanism of Fluxionality of the Clusters (n = 1 or 2)
Mann, Brian E.,Vargas, Maria D.,Khadar, Rayesh
, p. 1725 - 1728 (1992)
The carbonyl clusters, and , have been synthesised by replacement of the bromide in - by the appropriate phosphorous ligand.It is shown that and exist in s
