1407505-32-1

Basic information

• Product Name: C₃₅H₅₁ClN₄Si₂
• Synonyms: C₃₅H₅₁ClN₄Si₂
• CAS NO: 1407505-32-1
• Molecular Weight: 619.441
• Mol File: 1407505-32-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₅H₅₁ClN₄Si₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₅H₅₁ClN₄Si₂(1407505-32-1)
• EPA Substance Registry System: C₃₅H₅₁ClN₄Si₂(1407505-32-1)

Safety Data

• Hazardous Substances Data: 1407505-32-1(Hazardous Substances Data)

Upstream product

• 1309944-27-1 C₁₅H₂₇Cl₂NSi₂ 
• 151515-23-0 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene 
• 3032-92-6 4-cyanophenylacetylene 

Downstream Products

• 162408-77-7 1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium chloride 
• 24544-04-5 2,6-diisopropylbenzenamine 

Relevant articles and documents

Metal-free, stereospecific bis-silylation of functionalized alkynes with NHC-supported silylaminosilylene

The NHC-supported silylaminosilylene Ar(SiMe3)N(Cl)Si(IiPr) (1; Ar = 2,6-iPr2C6H3, IiPr = 1,3-diisopropyl-4,5- dimethylimidazol-2-ylidene) is an efficient and stereospecific bis-silylation reagent for a range of functionalized alkynes to yield cis-1,2-bis-silylated alkenes via a 1,4-silyl migration from the amino nitrogen atom to an alkyne carbon atom. The reaction is regio- and stereospecific for terminal alkynes with an electron-withdrawing substituent, thus providing a facile access to 1,2-bis-silylated alkenes with two different silyl groups.