1407797-77-6

Basic information

• Product Name: (R)-[(6-cyclohexyl-7-octen-1-yl)oxy]triisopropylsilane
• Synonyms: (R)-[(6-cyclohexyl-7-octen-1-yl)oxy]triisopropylsilane
• CAS NO: 1407797-77-6
• Molecular Weight: 366.703
• Mol File: 1407797-77-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-[(6-cyclohexyl-7-octen-1-yl)oxy]triisopropylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-[(6-cyclohexyl-7-octen-1-yl)oxy]triisopropylsilane(1407797-77-6)
• EPA Substance Registry System: (R)-[(6-cyclohexyl-7-octen-1-yl)oxy]triisopropylsilane(1407797-77-6)

Safety Data

• Hazardous Substances Data: 1407797-77-6(Hazardous Substances Data)

Upstream product

• 58649-22-2 (Z)-(3-chloro-1-propen-1-yl)cyclohexane 
• 1258222-46-6 C₂₂H₄₅BOSi 
• 931-48-6 2-cyclohexylacetylene 
• 42134-54-3 3-cyclohexyl-2-propyn-1-ol 
• 42134-55-4 (Z)-3-cyclohexyl-2-propene-1-ol 
• 183440-00-8 triisopropyl(pent-4-en-1-yloxy)silane 

Relevant articles and documents

Copper-catalyzed enantioselective allylic cross-coupling with alkylboranes

Abstract We have presented full details of our work on alkylboranes, which we have introduced as new reagents for copper-catalyzed SN2′-type enantioselective allylic substitutions. The copper catalysis delivered enantioenriched chiral products containing tertiary or quaternary carbon stereogenic centers branched with functionalized sp3-alkyl groups. The wide availability of alkylboranes via the established alkene hydroboration reaction is an attractive feature of these transformations. Various functional groups are tolerated in the substrates. A reaction pathway involving addition-elimination of a neutral alkylcopper(I) species with the allyl chloride substrate is proposed.