1408286-13-4Relevant academic research and scientific papers
DIRECT ANTI-MARKOVNIKOV ADDITION OF ACIDS TO ALKENES
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Page/Page column 13-16, (2013/12/03)
A method of making an anti-Markovnikov addition product is carried out by reacting an acid with an alkene or alkyne in a dual catalyst reaction system to the exclusion of oxygen to produce said anti-Markovnikov addition product; the dual catalyst reaction system comprising a single electron oxidation catalyst in combination with a hydrogen atom donor catalyst. Compositions useful for carrying out such methods are also described.
Direct catalytic anti-markovnikov hydroetherification of alkenols
Hamilton, David S.,Nicewicz, David A.
, p. 18577 - 18580 (2013/01/15)
A direct intramolecular anti-Markovnikov hydroetherification reaction of alkenols is described. By employing catalytic quantities of commercially available 9-mesityl-10-methylacridinium perchlorate and 2-phenylmalononitrile as a redox-cycling source of a
