140889-91-4Relevant academic research and scientific papers
Synthesis and Reactivity of Phosphonato, Phosphato and Arsonato Complexes of Platinum(II)
Kemmit, Raymond D. W.,Mason, Simon,Fawcett, John,Russell, David R.
, p. 851 - 858 (2007/10/02)
Treatment of the complexes cis-PtCl2L2> (L = donor ligand) with phenylphosphonic acid, methylphosphonic acid, phenyldihydrophosphate or phenylarsonic acid in the presence of an excess of silver(I) oxide in refluxing dichloromethane yielded the new metallacycles , or respectively.The X-ray crystal structure of showed the presence of a slightly puckered metallacyclic ring with the phosphoryl oxygen adopting an equatorial position.A decomposition product of the complex in solution was shown, via an X-ray crystal structure determination, to be the diorthometallated complex .
