140901-68-4

Basic information

• Product Name: (+/-)-5-endo-Acetoxymethyl-3-exo-hydroxy-2-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane
• CAS NO: 140901-68-4
• Molecular Weight: 355.412
• Mol File: 140901-68-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-5-endo-Acetoxymethyl-3-exo-hydroxy-2-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-5-endo-Acetoxymethyl-3-exo-hydroxy-2-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane(140901-68-4)
• EPA Substance Registry System: (+/-)-5-endo-Acetoxymethyl-3-exo-hydroxy-2-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane(140901-68-4)

Safety Data

• Hazardous Substances Data: 140901-68-4(Hazardous Substances Data)

Upstream product

• 88517-51-5 7-oxabicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid methyl ester 
• 89898-05-5 (1RS,2SR,4RS)-7-oxabicyclo[2.2.1]hept-5-ene-2-methanol 
• 127-65-1 chloroamine-T 
• 140901-67-3 (+/-)-2-endo-Acetoxymethyl-7-oxabicyclo<2.2.1>hept-5-ene 

Downstream Products

• 140901-70-8 (+/-)-5-endo-Acetoxymethyl-3-exo-methylsulfonyloxy-2-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 
• 140901-78-6 DL-(1,2,3/4,6)-3-Acetamido-6-acetoxymethyl-1,2-di-O-acetyl-4-bromo-1,2-cyclohexanediol 
• 140854-92-8 (+/-)-2-exo-(p-tolylsulfonylamino)-4,8-dioxatricyclo<4.2.1.0^3,7>nonane 
• 140901-69-5 (+/-)-3-exo-Acetoxy-5-endo-acetoxymethyl-2-exo-p-toluenesulfonamido-7-oxabicyclo<2.2.1>heptane 

Relevant articles and documents

Synthesis of Amino-5a-carba-deoxyhexopyranoses from 2(3)-Acetoxy-5-acetoxymethyl-3(2)-p-toluenesulfonamido-7-oxabicycloheptanes

cis-Hydroxyamination of endo-2-acetoxymethyl-7-oxabicyclohept-5-ene (1) under Sharpless condition affords two positional isomers 3 and 7 of 5-endo-acetoxymethyl-2(3)-exo-hydroxy-3(2)-exo-p-toluenesulfonamido-7-oxabicycloheptanes.Cleavage of