14093-56-2Relevant academic research and scientific papers
Regioselective and enantioselective iridium-catalyzed allylation of enamines
Weix, Daniel J.,Hartwig, John F.
, p. 7720 - 7721 (2007)
A highly enantioselective and regioselective monoallylation of the enamines of methyl ketones has been developed. After hydrolysis of the enamine (NaOAc/AcOH(aq)), the desiredallylated ketones were obtained in high yields (64-91% isolated yield
Electrochemical properties and reactions of organoboronic acid esters containing unsaturated bonds at their α-position
Ohtsuka, Kazuhiro,Inagi, Shinsuke,Fuchigami, Toshio
, p. G23 - G28 (2017/12/26)
Electrochemical analyses of 2-(cynnamyl)boronic acid pinacol ester and (3-phenyl-2-propynyl)boronic acid pinacol ester, and their trimethylsilyl analogues as well as their parent compounds were comparatively studied by cyclic voltammetry measurements. We
o-benzenedisulfonimide as reusable bronsted acid catalyst for acid-catalyzed organic reactions
Barbero, Margherita,Cadamuro, Silvano,Dughera, Stefano,Venturello, Paolo
, p. 1379 - 1388 (2008/12/21)
Acid-catalyzed organic reactions, such as etherification, esterification, acetal synthesis, cleavage, and interconversion, and pinacol rearrangement were carried out in the presence of catalytic amounts of o-benzenedisulfonimide as Bronsted acid catalyst; the conditions were mild and selective. The catalyst was easily recovered and purified, ready to be used in further reactions, with economic and ecological advantages. Georg Thieme Verlag Stuttgart.
