1409972-55-9

Upstream product

• 673-32-5 1-Phenylprop-1-yne 
• 333-27-7 methyl trifluoromethanesulfonate 
• 1383572-25-5 2,2'-(azanediylbis(3-methyl-6,1-phenylene))-bis(1,1,1,3,3,3-hexafluoropropan-2-ol) 
• 27996-13-0 α,α'-dibromo-di-p-tolylamine 

Relevant academic research and scientific papers

Unusually stable tungstenacyclobutadienes featuring an ONO trianionic pincer-type ligand

This report presents the synthesis of the first neutral trianionic ONO pincer-type tungsten alkylidyne complex, [CF3-ONO]WC( tBu)(OEt2) (5) {where CF3-ONO = (MeC 6H3[C(CF3)2

ONO PINCER LIGANDS AND ONO PINCER LIGAND COMPRISING METAL COMPLEXES

Embodiments of the invention are directed to ONO pinccr ligands that can be in a trianionic, protonated or protonated equivalent form. The ONO pincer ligand can be combined with a transition metal comprising compound to form an ONO pincer ligand comprising transition metal complex. By choice of the ONO pincer ligand structure, the steric and electronic properties of the transition metal complexes therefrom can be controlled. The ONO pincer ligands comprise a central nitrogen atom that is disubstituted with a pair of three atom comprising bridges where the three atoms are three sp2 hybridized carbons or the three atoms are a pair of sp2 hybridized carbons and an sp3 hybridized carbon or silicon.