141037-23-2

Basic information

• Product Name: Guanidine, [1-(4-chloro-2-methylphenyl)-4,5-dihydro-5-oxo-4,4-diphenyl-1H-imidaz ol-2-yl]-
• CAS NO: 141037-23-2
• Molecular Formula: C23H20ClN5O
• Molecular Weight: 417.898
• Mol File: 141037-23-2.mol

Chemical Properties

• CAS DataBase Reference: Guanidine, [1-(4-chloro-2-methylphenyl)-4,5-dihydro-5-oxo-4,4-diphenyl-1H-imidaz ol-2-yl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Guanidine, [1-(4-chloro-2-methylphenyl)-4,5-dihydro-5-oxo-4,4-diphenyl-1H-imidaz ol-2-yl]-(141037-23-2)
• EPA Substance Registry System: Guanidine, [1-(4-chloro-2-methylphenyl)-4,5-dihydro-5-oxo-4,4-diphenyl-1H-imidaz ol-2-yl]-(141037-23-2)

Safety Data

• Hazardous Substances Data: 141037-23-2(Hazardous Substances Data)

Upstream product

• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 79868-83-0 C₉H₁₂ClN₅ 

Relevant articles and documents

Reactions of Arylbiguanides with Benzoin at the pH of the Biguanide Bases

Arylbiguanides 2 a-e react with benzoin (1) at the pH of the base to two different products. 1 undergoes in presence of the base 2 a-e oxidation to benzil and benzoic acid, which reacts fast with the arylbiguanides 2 a-e to yield N-benzamides 3 a-d.After lowering the pH of the reacion mixture, the bases 2 b-e react with benzil to yield 2-guanidine 4 b-e.The mechanism of the formation is discussed.The structure of 4b was established from a single crystal x-ray structure analysis.The analysis was carried out at 100 K: C23H21N5O, Mr=383.5, monoclinic, C 2/c, a=15.842(6), b=8.419(3), c=30.223(10) Angstroem, β=98.44(3) deg, V=3987.3(9) Angstroem3, Z=8, dx=1.277 g/cm3, μ=0.81 cm-1, R=5.89percent, Rw=4.97percent (1537 observations, 233 parameters).Keywords.Benzoin, reaction with arylbiguanides; Triazines (N-benzamide); Imidazoles (2-guanidine); Synthesis; NMR-data; X-ray analysis.