141077-51-2Relevant academic research and scientific papers
Chiral silver phosphate-catalyzed cycloisomeric kinetic resolution of α-allenic alcohols
Wang, Yan,Zheng, Kuan,Hong, Ran
supporting information; experimental part, p. 4096 - 4099 (2012/04/10)
A kinetic resolution of α-allenic alcohols is realized through chiral silver phosphate-catalyzed cycloisomerization with high stereoselectivity (selectivity factor up to 189) and tolerance of a variety of functional groups. A mechanistic model is proposed to interpret the origin of the high stereoselectivity and broad substrate scope.
Palladium-catalyzed asymmetric arylation of 2,3-dihydrofuran: 1,8-Bis(dimethylamino)naphthalene as an efficient base
Ozawa, Fumiyuki,Kubo, Akihiko,Hayashi, Tamio
, p. 1485 - 1488 (2007/10/02)
Reaction of 2,3-dihydrofuran with aryl triflate (1) in the presence of a base and a palladium catalyst, generated in situ from Pd(OAc)2 and (R)-BINAP, gave (R)-2-aryl-2,3-dihydrofuran (2) and a small amount of (S)-2-aryl-2,5-dihydrofuran (3). T
