141077-75-0Relevant academic research and scientific papers
Optically Active Organoiron Complexes in Synthesis. An Enantioface Selective 3-Hydroxypropionate-2,3-Dication Equivalent
Chu, Kai-Hsuan,Zhen, Weiguo,Zhu, Xiao-Ya,Rosenblum, Myron
, p. 1173 - 1176 (1992)
The use of organoiron complexes 8 and 9 as chiral 3-hydroxypropionate-2,3-dication equivalents is illustrated by a sequence of transformations involving successive addition of nucleophiles to these cations, followed by redox promoted carboxylation to give 2R,3S-methyl 3-hydroxypentanoate and ent-sitophilate. Key Words: enantioface; 3-hydroxypropionate; sitophilate; organoiron; dication
