
Tetrahedron Letters p. 1173 - 1176 (1992)
Update date:2022-09-26
Topics:
Chu, Kai-Hsuan
Zhen, Weiguo
Zhu, Xiao-Ya
Rosenblum, Myron
The use of organoiron complexes 8 and 9 as chiral 3-hydroxypropionate-2,3-dication equivalents is illustrated by a sequence of transformations involving successive addition of nucleophiles to these cations, followed by redox promoted carboxylation to give 2R,3S-methyl 3-hydroxypentanoate and ent-sitophilate. Key Words: enantioface; 3-hydroxypropionate; sitophilate; organoiron; dication
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Doi:10.2174/157017812803521081
(2012)Doi:10.1246/cl.2011.1456
(2011)Doi:10.1039/c6ra01992g
(2016)Doi:10.1016/S0040-4020(01)90973-1
(1992)Doi:10.1021/jo00041a026
(1992)Doi:10.3987/COM-91-5918
(1992)