Optically Active Organoiron Complexes in Synthesis. An Enantioface Selective 3-Hydroxypropionate-2,3-Dication Equivalent

DOI: 10.1016/S0040-4039(00)91888-4

Source and publish data:

Tetrahedron Letters p. 1173 - 1176 (1992)

Update date:2022-09-26

Topics:

Authors:

Chu, Kai-Hsuan

Zhen, Weiguo

Zhu, Xiao-Ya

Rosenblum, Myron

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Article abstract of DOI:10.1016/S0040-4039(00)91888-4

The use of organoiron complexes 8 and 9 as chiral 3-hydroxypropionate-2,3-dication equivalents is illustrated by a sequence of transformations involving successive addition of nucleophiles to these cations, followed by redox promoted carboxylation to give 2R,3S-methyl 3-hydroxypentanoate and ent-sitophilate. Key Words: enantioface; 3-hydroxypropionate; sitophilate; organoiron; dication

Full text of DOI:10.1016/S0040-4039(00)91888-4

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