1410840-77-5

Basic information

• Product Name: tert-butyl 1-(2-ethoxy-2-oxoethyl)cyclohexa-2,5-dienecarboxylate
• Synonyms: tert-butyl 1-(2-ethoxy-2-oxoethyl)cyclohexa-2,5-dienecarboxylate
• CAS NO: 1410840-77-5
• Molecular Weight: 266.337
• Mol File: 1410840-77-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-butyl 1-(2-ethoxy-2-oxoethyl)cyclohexa-2,5-dienecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 1-(2-ethoxy-2-oxoethyl)cyclohexa-2,5-dienecarboxylate(1410840-77-5)
• EPA Substance Registry System: tert-butyl 1-(2-ethoxy-2-oxoethyl)cyclohexa-2,5-dienecarboxylate(1410840-77-5)

Safety Data

• Hazardous Substances Data: 1410840-77-5(Hazardous Substances Data)

Upstream product

• 774-65-2 benzoic acid tert-butyl ester 
• 105-36-2 ethyl bromoacetate 

Downstream Products

• 1410840-10-6 2-(1-(tert-butoxycarbonyl)cyclohexa-2,5-dien-1-yl)acetic acid 
• 1410840-12-8 2-(1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dien-1-yl)acetic acid 
• 1410840-18-4 7-bromo-3a-(((tert-butyldiphenylsilyl)oxy)methyl)-3,3a,7,7a-tetrahydrobenzofuran-2(6H)-one 
• 68654-50-2 1-Ethoxycarbonylmethyl-1-carboxy-cyclohexadien-(2,5) 

Relevant articles and documents

Catalytic desymmetrization of cyclohexadienes by asymmetric bromolactonization

Asymmetric bromolactonization of prochiral cyclohexadiene derivatives with N-bromosuccimide proceeded in the presence of (DHQD)2PHAL as a chiral catalyst to afford the corresponding bromolactones with up to 93% ee. This reaction was also applicable to the kinetic resolution of a racemic cyclic ene-carboxylic acid, where the starting material was recovered with high enantioselectivity.