141091-07-8Relevant academic research and scientific papers
An Intramolecular Schmidt Reaction of an Alkyl Azide with a Carbocation. The Generation and Rearrangement of a Conformationally Restricted Secondary Aminodiazonium Ion
Pearson, William H.,Schkeryantz, Jeffrey M.
, p. 5291 - 5294 (2007/10/02)
Treatment of azidoalkene 2 with triflic acid produced the bridged bicyclic enamine 3 by an intramolecular Schmidt reaction.Rearrangement of the intermediate aminodiazonium ion 5 is completely regioselective.
Lithium Perchlorate-Assisted Substitution Reactions of A11llylic Acetates and Allylic Alcohols
Pearson, William H.,Schkeryantz, Jeffrey M.
, p. 2986 - 2987 (2007/10/02)
Substitution reactions of allylic acetates and allylic alcohols by a variety of nucleophiles proceed smoothly in the presence of lithium perchlorate in ether, providing a convenient alternative to transition metal catalyzed methods.
