14112-80-2Relevant academic research and scientific papers
Aluminium triflate: an efficient recyclable Lewis acid catalyst for the aminolysis of epoxides
Williams, D. Bradley G.,Lawton, Michelle
, p. 6557 - 6560 (2007/10/03)
Epoxides are powerful starting materials for a range of useful materials and can be converted into, amongst others, amino alcohols. In this work, a range of epoxides was ring-opened using various alkyl- and arylamines under the action of aluminium triflat
A new and efficient epoxide ring opening via poor nucleophiles: Indole, p-nitroaniline, borane and O-trimethylsilylhydroxylamine in lithium perchlorate
Heydari, Akbar,Mehrdad, Morteza,Maleki, Aziz,Ahmadi, Nafiseh
, p. 1563 - 1565 (2007/10/03)
Highly regioselective ring opening of 2,3-dimethyloxirane, 2-epoxyphenylether and allyl(2-epoxymethyl) ether are observed through reactions with poor nucleophiles such as indole, borane, O-trimethylsilylhydroxylamine, p-nitroaniline and sterically hindered tert-butylamine in the presence of 5.0 M lithium perchlorate-Et2O solution. These reactions are fast, convenient, with rather high yields and are carried out at ambient temperatures.
