14116-78-0 Usage
Description
1(2H)-Naphthalenone, 3,4,4a,5,8,8a-hexahydrois a chemical compound characterized by its molecular formula C10H12O. It presents as a white to off-white solid with a faint odor, and it is recognized for its role as an intermediate in the production of other chemicals.
Uses
Used in Pharmaceutical Synthesis:
1(2H)-Naphthalenone, 3,4,4a,5,8,8a-hexahydrois utilized as a building block in the synthesis of pharmaceuticals. Its structural properties make it a valuable component in the development of new drugs and medicines.
Used in Agrochemical Production:
In the agrochemical industry, 1(2H)-Naphthalenone, 3,4,4a,5,8,8a-hexahydrois employed as an intermediate for the creation of various agrochemicals, contributing to the development of products that enhance agricultural productivity.
Used in Fine Chemicals Synthesis:
1(2H)-Naphthalenone, 3,4,4a,5,8,8a-hexahydrois also used as a fundamental component in the synthesis of fine chemicals, which are high-purity chemicals used in various applications, including fragrances, dyes, and coatings.
Used in Material Development:
1(2H)-Naphthalenone, 3,4,4a,5,8,8a-hexahydrohas been investigated for its potential in the development of new materials, suggesting its versatility and applicability in a range of industrial and research contexts.
Used in Chemical Research:
1(2H)-Naphthalenone, 3,4,4a,5,8,8a-hexahydrois known for its application in chemical research, where it aids in the study and understanding of various chemical reactions and processes, further expanding its utility in the scientific community.
Safety Note:
Despite its low toxicity, it is crucial to follow proper handling and safety protocols when working with 1(2H)-Naphthalenone, 3,4,4a,5,8,8a-hexahydroto ensure the well-being of individuals and the environment.
Check Digit Verification of cas no
The CAS Registry Mumber 14116-78-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,1,1 and 6 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 14116-78:
(7*1)+(6*4)+(5*1)+(4*1)+(3*6)+(2*7)+(1*8)=80
80 % 10 = 0
So 14116-78-0 is a valid CAS Registry Number.
14116-78-0Relevant articles and documents
Diels-Alder Reactions of Cycloalkenones. 3. Effects of Specific Reaction Parameters
Fringuelli, Francesco,Pizzo, Ferdinando,Taticchi, Aldo,Wenkert, Ernest
, p. 2802 - 2808 (1983)
The effects of the Lewis acid-ketone complexation time and temperature, the nature and amount of catalyst, and the concentrations of ketone and diene on the Diels-Alder reactions of 2-cyclopentenones, 2-cyclohexenones, and 2-cycloheptenones with 1,3-butadiene, isoprene, and (E)-piperylene are described.
A straightforward route to functionalized trans-diels-alder motifs
Lee, Jun Hee,Zhang, Yandong,Danishefsky, Samuel J.
supporting information; experimental part, p. 14330 - 14333 (2010/12/25)
A sequence consisting of a Lewis acid-catalyzed Diels-Alder reaction on a 2-halocyclohexenone, followed by reductive alkylation, provides a route to trans-fused octalinones bearing angular methyl groups with functionality corresponding to that which would have been possible from a trans-directed Diels-Alder reaction.
Synthesis of cyclopropyl silyl ethers and their facile ring opening by photoinduced electron transfer as key step in radical/radical cationic cascade reactions
Waske, Prashant A.,Mattay, Jochen
, p. 10321 - 10330 (2007/10/03)
Various ring-fused cyclopropyl silyl ethers with an benzylic, olefinic or acetylenic side chain have been synthesized. Upon oxidative photoinduced electron transfer (PET) the cyclopropane ring opens and forms a reactive β-keto radical, which undergoes intramolecular cyclization. In some cases we observed only formation of ring opened non-cyclized products. With olefinic side chain 5-exo-trig mode of cyclization rather than 6-endo-trig mode of cyclization takes place whereas in case of acetylenic side chain we observed 6-endo cyclization.
