141208-06-2

Basic information

• Product Name: 2-Propenamide, N-methoxy-N-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (E)-
• CAS NO: 141208-06-2
• Molecular Formula: C14H23NO2
• Molecular Weight: 237.342
• Mol File: 141208-06-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Propenamide, N-methoxy-N-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenamide, N-methoxy-N-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (E)-(141208-06-2)
• EPA Substance Registry System: 2-Propenamide, N-methoxy-N-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (E)-(141208-06-2)

Safety Data

• Hazardous Substances Data: 141208-06-2(Hazardous Substances Data)

Usage

Use

Insecticide and acaricide

Target pests

Ticks, mites, and other pests

Mode of action

Disrupts nervous system, leading to paralysis and death

Toxicity

Relatively low toxicity to humans and animals

Applications

Pest control in agricultural and veterinary settings

Upstream product

• 124931-12-0 diethyl (N-methoxy-N-methylcarbamoylmethyl)phosphonate 
• 432-25-7 2,6,6-trimethylcyclohex-1-enecarbaldehyde 
• 14393-45-4 (E)-3-(2,6,6-trimethylcyclohex-1-enyl)acrylic acid 
• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 
• 80922-54-9 (E)-3-(2,6,6-Trimethyl-1-cyclohexen-1-yl)-2-propensaeure-ethylester 

Downstream Products

• 88981-43-5 1-chloro-4-(2,6,6-trimethylcyclohexenyl)-3-butenoate 
• 87975-87-9 (6E)-7-(2,6,6-trimethyl-1-cyclohexen-1-yl)-6-hepten-5-one 
• 63429-28-7 (4E)-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-4-penten-3-one 
• 65868-79-3 (2E)-3-1-phenyl-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propen-1-one 
• 53163-45-4 [1,1,1-2H₃]-(3E)-4-(2,6,6-trimethylcyclohex-1-enyl)but-3-en-2-one 
• 79-77-6 (E)-β-ionone 
• 40244-49-3 ethyl 3-methyl-5-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-2,4-dienoate 
• 40244-66-4 ethyl 3-methyl-5-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-2,4-dienoate 
• 29789-62-6 (2Z,4E)-ethyl 3-methyl-5-(2,6,6-trimethylcyclohex-1-enyl)penta-2,4-dienoate 
• 4808-03-1 ethyl (2E,4E)-5-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-2,4-dienoate 
• 17974-55-9 (2E,4E)-ethyl 3-methyl-5-(2,6,6-trimethylcyclohex-1-enyl)penta-2,4-dienoate 
• 53018-97-6 (E)-3-(2,6,6-Trimethyl-cyclohex-1-enyl)-propenal 
• 87355-47-3 all-E (19-⁽¹³⁾C)retinal 
• 141208-07-3 C₁₉⁽¹³⁾CH₂₇N 

Relevant articles and documents

Photocatalytic e → Z Isomerization of β-Ionyl Derivatives

An operationally simple E → Z isomerization of activated dienes, based on the β-ionyl motif intrinsic to retinal, is reported using inexpensive (-)-riboflavin (vitamin B2) under irradiation at 402 nm. Selective energy transfer from photoexcited (-)-riboflavin to the starting E-isomer enables geometrical isomerization. Since the analogous process with the Z-isomer is inefficient, microscopic reversibility is circumvented, thereby enabling a directional isomerization to generate the contra-thermodynamic product (up to 99% yield, up to 99:1 Z/E). Prudent choice of photocatalyst enables chemoselective isomerization to be achieved in both inter- and intramolecular systems. The principles established from this study, together with a molecular editing approach, have facilitated the development of a regioselective isomerization of a truncated triene based on the retinal scaffold.

Retinoids and related compounds. Part 22. Synthesis of β-ionone analog tricarbonyliron complexes

The synthesis of β-ionone analog tricarbonyliron complexes was investigated. N-Methoxy-N-methyl-(2,6,6-trimethyl-1-clohexen-1-yl)-2- propenamide (Weinreb amide), prepared from the corresponding ethyl ester and N,O-dimethylhydroxylamine hydrochloride, reacted smoothly with various organometallic reagents to afford the β-ionone analogs in good to excellent yields. Treatment of these compounds with dodecacarbonyltriiron afforded the corresponding tricarbonyliron complexes in high yields.