141221-89-8Relevant articles and documents
Synthesis of dibenz[b,f]oxepins via manganese(III)-based oxidative 1,2-radical rearrangement
Cong, Zhiqi,Miki, Takumi,Urakawa, Osamu,Nishino, Hiroshi
scheme or table, p. 3978 - 3981 (2009/10/14)
(Chemical Equation Presented) The oxidation of monoalkyl 2-(9H-xanthenyl)malonates 1 with Mn(OAc)3 gave the 9- or 10-dibenz[b,f]oxepincarboxylates 2 in good yields. The reaction proceeds with high regioselectivity except for the case of (1-meth