141240-88-2Relevant academic research and scientific papers
Enantioselective relay catalytic cascade intramolecular hydrosiloxylation and mukaiyama aldol reaction
Wang, Pu-Sheng,Li, Kang-Nan,Zhou, Xiao-Le,Wu, Xiang,Han, Zhi-Yong,Guo, Rui,Gong, Liu-Zhu
supporting information, p. 6234 - 6238 (2013/07/05)
Cascading chemistry! The first practical relay catalytic cascade intramolecular hydrosiloxylation of arylacetylene and asymmetric Mukaiyama aldol reaction has been established to give synthetically useful products in high yields and with excellent ee (see scheme). Copyright
Silaindene - eine einfache Synthese
Maerkl, G.,Berr, K.-P.
, p. 1601 - 1604 (2007/10/02)
Tolanes substituted in o-position by -SiHPh2, polymerize intermolecular with H2PtCl6/CH2Cl2 as catalyst, depolymerisation at 350-380 deg C/1 torr yields the silaindenes.
