141244-65-7

Upstream product

• 72681-08-4 (E)-3-methyl-5-phenyl-pent-2-en-1-ol 
• 106730-50-1 2-acetoxy-ethanesulfinyl chloride 
• 36805-43-3 ethyl (E)-3-methyl-5-phenylpent-2-enoate 
• 2550-26-7 4-Phenyl-2-butanone 

Downstream Products

• 141244-66-8 3-methyl-5-phenyl-1-pentene-3(β-acetoxy)ethyl sulfone 
• 141244-67-9 3-methyl-5-phenyl-1-pentene-3(β-amino)ethyl sulfone 
• 141357-19-9 3-methyl-5-phenyl-1-pentene-3(β-guanidino)ethyl sulfone-sulfonate 

Relevant academic research and scientific papers

-Sigmatropic rearrangement of allylic sulfinate esters: A novel synthesis of agelasidine-A analogues

Sulfonylguanidino analogues 3,7-dimethyl-1,6-octadiene-3(β-guanidino)ethylsulfone sulfonate (4), 3,6-dimethyl-1-heptene-3(β-guanidino)ethylsulfone sulfonate (5), 3-methyl-5-phenyl--1-pentene-3(β-guanidino)ethylsulfone sulfonate (6) of agelasidine (1) have been synthesized in high yields using -sigmatropic rearrangement of allylic sulfinate esters as a key reaction.