141246-79-9Relevant academic research and scientific papers
A Diastereoselective Route to Functionalised Epoxides by Reduction of Cyclic β-Ketosulphoxides
Armer, Richard,Simpkins, Nigel S.
, p. 363 - 366 (2007/10/02)
A thiane oxide system 1, bearing a protected hydroxyl group, undergoes stereoselective acylation to give a range of β-ketosulphoxides 2a-e, which can then be reduced stereoselectively to give either of the corresponding hydroxysulphoxides 3 and 4.Further
Stereoselective Synthesis using Oxide System as a Disposable Template
Armer, Richard,Begley, Michael J.,Cox, Paul J.,Persad, Andrew,Simpkins, Nigel S.
, p. 3105 - 3112 (2007/10/02)
Substitution of the thiane oxide 1, via the corresponding α-sulfinyl carbanion, has been explored as a means of obtaining a range of functionalised products in stereoselective fashion.Whereas reaction of the α-sulfinyl carbanion derived from 1 with either
