14125-77-0

Basic information

• Product Name: 1,5-Anhydro-2,3,4-tri-O-benzoyl-D-threo-pent-1-enitol
• Synonyms: 1,5-Anhydro-2,3,4-tri-O-benzoyl-D-threo-pent-1-enitol
• CAS NO: 14125-77-0
• Molecular Weight: 444.441
• Mol File: 14125-77-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,5-Anhydro-2,3,4-tri-O-benzoyl-D-threo-pent-1-enitol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-Anhydro-2,3,4-tri-O-benzoyl-D-threo-pent-1-enitol(14125-77-0)
• EPA Substance Registry System: 1,5-Anhydro-2,3,4-tri-O-benzoyl-D-threo-pent-1-enitol(14125-77-0)

Safety Data

• Hazardous Substances Data: 14125-77-0(Hazardous Substances Data)

Upstream product

• 14262-83-0 2,3,4-tri-O-benzoyl-α-D-xylopyranosyl bromide 
• 176380-15-7 S-phenyl 2,3,4-tri-O-benzoyl-1-deoxy-1-thio-β-D-xylopyranoside 
• 22435-09-2 1,2,3,4-tetra-O-benzoyl-β-D-xylopyranoside 
• 98-88-4 benzoyl chloride 

Downstream Products

• 84679-46-9 (+)-(5S)-3,5-Bis(benzoyloxy)-5,6-dihydro-2H-pyran-2-one 
• 122359-46-0 C₂₆H₁₉ClO₈ 
• 52080-51-0 2,3,4-Tri-O-benzoyl-2-C-chloro-α-D-lyxopyranosyl chloride 
• 52080-51-0 2,3,4-tri-O-benzoyl-2-chloro-2-deoxy-β-D-xylopyranosyl chloride 
• 73322-35-7 1,3,4-Tri-O-benzoyl-α-D-threo-pentopyranos-2-ulose 
• 73322-21-1 1,3-Di-O-benzoyl-4-deoxy-β-D-pent-3-enopyranos-2-ulose 
• 73322-31-3 2,3,4-Tri-O-benzoyl-2-C-bromo-α-D-lyxopyranosyl bromide 
• 73322-31-3 2,3,4-Tri-O-benzoyl-2-C-bromo-β-D-xylopyranosyl bromide 
• 87713-48-2 C₁₉H₁₅BrO₆ 
• 75414-19-6 2,3,4-di-O-benzoyl-1,5-anhydro-D-threo-pent-2-ulose E-oxime 
• 52080-51-0 2,3,4-Tri-O-benzoyl-2-C-chloro-α-D-xylopyranosyl chloride 
• 73322-25-5 4-Benzoyloxy-2-methoxy-2H-pyran-3(6H)-one 
• 73322-22-2 4-Benzoyloxy-2-chloro-2H-pyran-3(6H)-one 
• 73322-23-3 4-Benzoyloxy-2-bromo-2H-pyran-3(6H)-one 

Relevant articles and documents

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Mild cu(Otf)2-mediated C-glycosylation with chelation-assisted picolinate as a leaving group

C-Glycosylation reactions of glycosyl picolinates with allyltrimethylsilane or silyl enol ethers were developed. Picolinate as a chelation-assisted leaving group could be activated by Cu(OTf)2 and avoided the use of harsh Lewis acids. The glycosylations were operated under mild neutral conditions and gave the corresponding C-glycosides in up to 95% yield with moderate to excellent stereoselectivities.