14127-68-5Relevant articles and documents
Production of potentially prebiotic condensed phosphates by phosphorus redox chemistry
Pasek, Matthew A.,Kee, Terence P.,Bryant, David E.,Pavlov, Alexander A.,Lunine, Jonathan I.
, p. 7918 - 7920 (2009/04/12)
Bringing phosphorus to life: The prebiotic origin of key biomolecules such as RNA and ATP is contingent on a source of condensed phosphates, such as pyrophosphate and triphosphate. Condensed phosphates can be produced at high yields from the oxidation of H-phosphonate or H-phosphinate. Reactive phosphates were likely abundant on the early earth's surface, setting the stage for prebiotic chemistry that led to the evolution of life. (Figure Presented).
Synthesis of hexaphosphate by hydrolysis of cyclo-hexaphosphate
Watanabe, Makoto,Asai, Naoki,Sakurai, Makoto
, p. 387 - 394 (2007/10/03)
Sodium and ammonium hexaphosphates were prepared by hydrolyzing cyclo-hexaphosphate in a 10M sodium hydroxide solution at -7°C for 20h. Sodium hexaphosphate was amorphous and unstable at room temperature. Ammonium hexaphosphate was crystalline and stable at room temperature.
Ueber die Reaktion von Harnstoff mit Ammoniumhydrogenamidophosphat unter dem Atmosphaerendruck
Shimasaki, Choichiro,Hara, Mitsunari
, p. 3613 - 3616 (2007/10/02)
Die Reaktion von Harnstoff mit Ammoniumhydrogenamidophosphat (NH4HPO3NH2) im Schmelzzustand unter dem Atmosphaerendruck ergibt, dass die Bildung des Guanidinumions (GH+) zusammen mit dem Phosphation bei ca. 160
