1412914-75-0Relevant academic research and scientific papers
Total synthesis of aeruginosin 98B
Trost, Barry M.,Kaneko, Toshiyuki,Andersen, Neil G.,Tappertzhofen, Christoph,Fahr, Bruce
, p. 18944 - 18947 (2013/01/15)
The first total synthesis of aeruginosin 98B was accomplished. The key step is a highly diastereoselective Pd-catalyzed intramolecular asymmetric allylic alkylation reaction of a diastereomeric mixture of allylic carbonates that is enabled by the use of racemic phosphine ligand L1.
