141316-76-9Relevant academic research and scientific papers
DIISOPROPYL TARTRATE (E)-γ-(DIMETHYLPHENYLSILYL)ALLYLBORONATE, A CHIRAL ALLYLIC ALCOHOL β-CARBANION EQUIVALENT FOR THE ENANTIOSELECTIVE SYNTHESIS OF 2-BUTENE-1,4-DIOLS FROM ALDEHYDES
Roush, William R.,Grover, Paul T.
, p. 7567 - 7570 (1990)
An enantioselective synthesis of 4-substituted (E)-2-buten-1,4-diols is described.The method involves the reaction of aldehydes with the chiral PhMe2Si-substituted allylboronate 3 followed by epoxidation (dimethyl dioxirane) and acid catalyzed Petersen re
