DIISOPROPYL TARTRATE (E)-γ-(DIMETHYLPHENYLSILYL)ALLYLBORONATE, A CHIRAL ALLYLIC ALCOHOL β-CARBANION EQUIVALENT FOR THE ENANTIOSELECTIVE SYNTHESIS OF 2-BUTENE-1,4-DIOLS FROM ALDEHYDES

DOI: 10.1016/S0040-4039(00)97300-3

Source and publish data:

Tetrahedron Letters p. 7567 - 7570 (1990)

Update date:2022-08-03

Topics:

Authors:

Roush, William R.

Grover, Paul T.

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Article abstract of DOI:10.1016/S0040-4039(00)97300-3

An enantioselective synthesis of 4-substituted (E)-2-buten-1,4-diols is described.The method involves the reaction of aldehydes with the chiral PhMe2Si-substituted allylboronate 3 followed by epoxidation (dimethyl dioxirane) and acid catalyzed Petersen re

Full text of DOI:10.1016/S0040-4039(00)97300-3

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